Synthesis of Iron Oxide Nanoparticles Using Potassium Trioxalatoferrate[III] as a Single Source Precursor and its Application for Degradation of Organic Dyes
Ajay V Gole
Department of Chemistry, SVKM’s Mithibai College of Arts, Chauhan Institute of Science & Amrutben Jivanlal College of Commerce & Economics (Autonomous). Mumbai, India.
Hetal J Mehta
Department of Chemistry, SVKM’s Mithibai College of Arts, Chauhan Institute of Science & Amrutben Jivanlal College of Commerce & Economics (Autonomous). Mumbai, India.
Vidhi Vyas
Department of Chemistry, SVKM’s Mithibai College of Arts, Chauhan Institute of Science & Amrutben Jivanlal College of Commerce & Economics (Autonomous). Mumbai, India.
1-9
Vol: 14, Issue: 1, 2024
Receiving Date:
2023-11-10
Acceptance Date:
2024-01-18
Publication Date:
2024-01-19
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http://doi.org/10.37648/ijrst.v14i01.001
Abstract
Organic azo and vat dyes are widely used in textile industries and approximately 15-50% doesn’t adhere to garments during the dyeing process and are released into water bodies from industrial outlets. They are dangerous to the environment because they have an abhorrent impact on water bodies and soil microbial ecosystems. They can invade biotic life by moving up the food chain and public water supply systems. Long-term exposures have a detrimental impact on both human and aquatic health. Malachite green[MG], Methylene blue[MB], Vat yellow 1[VY], and Vat Brown RRD[VB] are among the dyes that are used very largely in textile industry. Here in we report synthesis of iron oxide nanoparticles by thermal decomposition of potassium trioxalatoferrate[III] as a single source precursor (SSP).The powder XRD shows (220) (311) (222) (422) (311) (440) with Cubic phase which matches with (JCPDS 19-0629). Particle size ranges from 30-50 nm. The prepared nanoparticles are used for photocatalytic degradation of dyes as it has a band gap between 2-3eV so one can employ it for sustainable development.
Keywords:
Iron oxides nanoparticles; single source precursor; toxic organic dyes; degradation
References
- C. N. R. Rao and J. Gopalkrishnan, “New directions in solid state chemistry”, Second edition, Cambridge University Press, 1997
- C. Jones and P. O’Brein; CVD of Compound Semiconductors, “Precursor Synthesis, Development and Applications”, VCH, 1997.
- A. V. Gole and S. S. Garje, “Advanced Materials Research,” vol. 383-390, pp. 3828-3835, 2011.
- A. V.. Gole, H. J. Mehta, “Emerging Technologies and Innovative Research”, Volume 9, Issue 5, pp. 500-507, 2022.
- A. V. Gole, H. J. Mehta, “Journal of Research and Analytical Reviews”, Volume 10, Issue 4, pp. 80-87, November, 2023.
- Z. Q. Li, Y. Ding, Y. J. Xiong, Q. Yang and Y. Xie, “Chem. Commun”, 918, pp. 5231-5233, 2005
- D. Dinsmore, M. F. Hsu, M. G. Nikolaides, M. Marquez, A. R. Bausch and D. A. Weitz, “Selectively Permeable Capsules Composed of Colloidal Particles”, Science, Vol. 298, pp. 1006, 2002.
- Z. Y. Zhong, Y. D. Yin, B. Gates and Y. N. Xia, “Preparation of Mesoscale Hollow Spheres of TiO2 and SnO2 by Templating Against Crystalline Arrays of Polystyrene Beads,” Adv. Mater., Vol. 12, pp. 206, 2000.
- K. T. Lee, Y. S. Jung and S. M. Oh, “Synthesis of Tin-Encapsulated Spherical Hollow Carbon for Anode Material in Lithium Secondary Batteries”, J. Am. Chem. Soc., Vol. 125, pp. 5652, 2003.
- N. Mufti, T. Atma, A. Fuad, E. Sutadji, “Synthesis and characterization of black, Red And Yellow nanoparticles pigments from the Iron sand”, AIP Conference Proceedings, Vol. 45, 2014
- Nandang Mufti, T. Atma, A. Fuad, “Synthesis and characterization of black, red and yellow nanoparticles pigments from the iron sand”
- S. Sun, C.B. Murray, D. Weller, L. Folks, A. Moser, “Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices”, Science 287, pp. 1989, 2000
- H.T. Pu, F.J. Jiang, “Towards high sedimentation stability: magnetorheological fluids based on CNT/Fe3O4 nanocomposites”, Nanotechnol, 16, pp. 1486, 2005.
- J. Tang, K.Y. Wang, W. Zhou, J, “Magnetic properties of nanocrystalline films”, Appl. Phys. 89, pp. 7690, 2001.
- D.K. Yi, S.S. Lee, J.Y. Ying, “Synthesis and characterization of black, red and yellow nanoparticles pigments from the iron sand”, Chem, Mater, 182459, 2006.
- Q.A. Pankhurst, J. Connolly, S.K. Jones, J. Dobson, J. Phys. D Appl. Phys, “Applications of magnetic nanoparticles in biomedicine”, Vol. 36, 2003.
- W. B. Mi, J. J. Shen, D. L. Hou, X. L. Li, E. Y. Jiang and H L Bai, J. Phys. D: Appl. Phys, “Structure, magnetic and transport properties of polycrystalline Fe3O4–Ge nanocomposite films”, 41 055009, 2008
- P.S. Bassi, Gurudayal, L. H. Wong, and J. Barber, Phys. Chem. Chem. Phys, “Iron based photoanodes for solar fuel production”, pp. 11834-11842, 2014.
- A Kumar, B Sahoo, A Montpetit, S Behera, R.F. Lockey, and S.S Mohapatra, Nanomedicine, “Development of hyaluronic acid-Fe2O3 hybrid magnetic nanoparticles for targeted delivery of peptides”, pp. 132-137, 2007.
- Lenka Kubíčková, Petr Brázda, Miroslav Veverka, Ondřej Kaman, Vít Herynek, Magda Vosmanská, Petr Dvořák, Karel Bernášek, Jaroslav Kohout, “Nanomagnets for ultra-high field MRI: Magnetic properties and transverse relaxivity of silica-coated ε-Fe2O3”, Volume 480, 15 June 2019, pp. 154-163
- Irfan Khan, Sakura Morishita, Ryuji Higashinaka, Tatsuma D. Matsuda, Yuji Aoki, Ernő Kuzmann, Zoltán Homonnay, Sinkó Katalin, Luka Pavić, Shiro Kubuki, “Synthesis, characterization and magnetic properties of ε-Fe2O3 nanoparticles prepared by sol-gel method”, Vol. 538, 2021,
- Z. Sheikholeslami, D. Yousefi Kebria, F. Qaderi, “Application of γ-Fe2O3 nanoparticles for pollution removal from water with visible light”, Journal of Molecular liquids, Vol 299(1), pp 112118, 2018.
- M. A. Howland, “History of Modern Clinical Toxicology”, Academic Press, 2021.
- A. Ashfaq and A. Khatoon, “Waste Management of Textiles: A Solution to the Environmental Pollution”, International Journal of Current Microbiological Applied Sciences, Vol. 3(7), pp 780-787, 2014.
- R. K. Verma, M.S. Sankhla, N. V. Rathod, S. S. Sonone, K. Parihar, G. K. Singh, “Eradication of Fatal Textile Industrial Dyes by Watewater Treatment”, Biointerface Research in Applied Chemistry, Vol 12(1), pp 567-587, 2022.
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