Details

To Study the Effect of Solvent on AC Conductivity and Dielectric Constant on Blend Formation of Poly (Styrene): Poly (Vinyl Acetate)

H G Pande

Department of Physics, Vidya Bharati Mahavidyalaya, Camp, C.K. Naidu Road, Amravati, Maharashtra, India

G T Lamdhade

Department of Physics, Vidya Bharati Mahavidyalaya, Camp, C.K. Naidu Road, Amravati, Maharashtra, India

40-47

Vol: 13, Issue: 1, 2023

Receiving Date: 2023-02-02 Acceptance Date:

2023-03-17

Publication Date:

2023-03-18

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http://doi.org/10.37648/ijrst.v13i01.006

Abstract

The main objective of this work is to illustrate miscibility, when formation of poly blends occurred in different solvents. Isothermal evaporation method was used to achieve poly blends of poly styrene and poly vinyl acetate (PS: PVAc).The FTIR spectroscopy results revel that there are miscibility exists. For these blends with different solvents, electrical conductivity and dielectric constant were measured at different temperatures (313K, 323K, 333K and 343K) and at the different frequencies (1 KHz to 10MHz) using 4284 LCR meter. It is found that ac conductivity of polyblends thin film varies with temperature for all values of frequencies and it varies with increase in frequencies at constant temperature. The dielectric constant also varies with the increasing of the temperature of polyblends.

Keywords: Solvents; Polystyrene (PS); Polyvinyl acetate (PVAc); Miscibility; AC Conductivity; Dielectric Constants.

References

  1. Cristovan, F. H., Paula, D. F. R., Lemos, S. G., De Oliveira, A. J. A., & Pereira, E. C. (2009). DC conductivity study of polyaniline and poly (acrylonitrile-butadiene-styrene) blends. Synthetic Metals, 159(21), 2188-2190. DOI: https://doi.org/10.1016/j.synthmet.2009.08.042
  2. I.S. Elashmawi, N.A. Hakeem, and E.M. Abdelrazek, (Oct 2008), Spectroscopic and thermal studies of PS/PVAc Blends; Physica B: Condensed Matter volume 403 issue 19-20, 3547 - 3552, https://doi.org/10.1016/j.physb.2008.05.024
  3. H. Rawal and S. Devi, (Dec 1993), Compatibility of Poly(styrene)/Poly(vinyl acetate) Blends; Polymer Journal, volume 25 issue 12, 1215 to 1221 https://doi.org/10.1295/polymj.25.1215
  4. S.G. Vidhale and N.G. Belsare, (2013), Effect of IR Radiation on the Dielectric Properties of Salicylic Acid Doped Poly- blend Thin Films of PS and PMMA; International Journal of Scientific & Engineering Research, Vol.4 [09].
  5. P.A.P. Mamza and B.T. Nwufo, (22 Jan 2010), Density and Morphological Properties of Some Reinforced Polymers; Nigerian Journal of Basic and Applied Sciences volume 17 issue 2, https://doi.org/10.4314/njbas.v17i2.49888
  6. M. M. Kummali, G. A. Schwartz, Angel Alegría, Richard Arinero, Juan Colmenero, (15 Sep 2011), Compatibility studies of polystyrene and poly(vinyl acetate) blends using electrostatic force microscopy; Journal of Polymer Science Part B: Polymer Physics volume 49 issue 18 pages 1332 - 1338, https://doi.org/10.1002/polb.22301.
  7. P.P. Raut, G.T. Lamdhade, F. C. Raghuwanshi, T. Shripathi, (2016) National Conference on Material Science and Renewable Energy Sources (NCMSRES) Proceeding, 200-202.
  8. N. G. Belsare, A.S. Wadatkar, R. V. Joat, T. S. Wasnik, F. C. Raghuwanshi, K. B. Raulkar, and G.T. Lamdhade, (2011), Polyvinyl chloride–polymethyl methacrylate micro-composite polymers: miscibility; Journal of Electron Devices, 11, 583-587.
  9. V.Rao, P.V Ashokan, M.H Shridhar, (April 2000), Studies of Dielectric Relaxation and A C Conductivity on Cellulose Acetate Hyderogen Phthalate-Poly(Methyl Methacrylate) Blends); Materials Science and Engineering: A; volume 281 issue 1-2,pages 213 to 220, https://doi.org/10.1016/s0921-5093(99)00723-6.
  10. Mohammad Saleem Khan, Raina Aman Qazi and Mian Said Wahid, (April, 2008), Miscibility studies of PVC/PMMA and PS/PMMA blends by dilute solution viscometry and FTIR; African Journal of Pure and Applied Chemistry, Vol. 2 (4), pages 041-045.
  11. H. Kaczmarek, (Nov 1995), Photodegradation of polystyrene and poly(vinyl acetate) blends—I. Irradiation of PS/PVAc blends by polychromatic light; European Polymer Journal volume 31 issue 11, 1037 - 1042, https://doi.org/10.1016/0014-3057(95)00094-1
  12. K. Prabha, H. S. Jayanna, (2015), Study the Frequency Dependence of Dielectric Properties of Gamma Irradiated PVA(1-x)PSx Polymer Blends; Open Journal of Polymer Chemistry volume 05 issue 04 , 47 - 54, https://doi.org/10.4236/ojpchem.2015.54006
  13. P. Dutta, S. Biswas, M. Ghosh, S. K. De and S. Chatterjee, (Jun 2001) The dc and ac conductivity of polyaniline–polyvinyl alcohol blends; Synthetic Metals volume 122 issue 2, 455 - 461, https://doi.org/10.1016/s0379-6779(00)00588-9.
  14. I.C. McNeill, (May 1997), Thermal degradation mechanisms of some addition polymers and copolymers; Journal of Analytical and Applied Pyrolysis; volume 40-41, 21- 41, https://doi.org/10.1016/s0165-2370(97)00006-5
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