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Historical Development, Synthetic Variables, Classification and Characterization Techniques of Polyoxometalates

Dr. K C Dey

Dean, Faculty of Science and Engineering, University Department of Chemistry, Kolhan University, Chaibasa, Jharkhand, India.

Pammi Kumari

Jamshedpur, Jharkhand, India

154-177

Vol: 7, Issue: 1, 2017

Receiving Date: 2017-01-11 Acceptance Date:

2017-02-07

Publication Date:

2017-03-07

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Abstract

Polyoxometalates represent a diverse family of metal oxide clusters having well defined structures with a large variation in size, metal-oxygen framework, elemental composition and unmatched properties. They are considered as one of the most attractive and growing area of research and development especially in the field of catalysis, material chemistry and biochemistry. This review paper starts with a brief introduction of POMs along with many reports and historical aspects. This also summarizes the synthetic and design approaches of various POM building- units encompassing the important synthetic variables like concentration of cation, pH, reaction temperature etc. On the development, it highlists the different sub-class of POMs along with their fundamental structural types with special focus on Keggin and Lindqvist structure. The final section is devoted for discussing the various cutting edge techniques and precise tools which enables the complete characterization of newly synthesizedPOMclusters.

Keywords: Polyoxometalates; Building-units; Synthetic Variables; Keggin Structure; Lindqvist Structure; Characterization techniques.

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