Historical Development, Synthetic Variables, Classification and Characterization Techniques of Polyoxometalates
Dr. K C Dey
Dean, Faculty of Science and Engineering, University Department of Chemistry, Kolhan University, Chaibasa, Jharkhand, India.
Pammi Kumari
Jamshedpur, Jharkhand, India
Receiving Date:
2017-01-11
Acceptance Date:
2017-02-07
Publication Date:
2017-03-07
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Abstract
Polyoxometalates represent a diverse family of metal oxide clusters having well defined structures with a large variation in size, metal-oxygen framework, elemental composition and unmatched properties. They are considered as one of the most attractive and growing area of research and development especially in the field of catalysis, material chemistry and biochemistry. This review paper starts with a brief introduction of POMs along with many reports and historical aspects. This also summarizes the synthetic and design approaches of various POM building- units encompassing the important synthetic variables like concentration of cation, pH, reaction temperature etc. On the development, it highlists the different sub-class of POMs along with their fundamental structural types with special focus on Keggin and Lindqvist structure. The final section is devoted for discussing the various cutting edge techniques and precise tools which enables the complete characterization of newly synthesizedPOMclusters.
Keywords:
Polyoxometalates; Building-units; Synthetic Variables; Keggin Structure; Lindqvist Structure; Characterization techniques.
References
- (a) M. T. Pope, A. Muller, Angew. Chem. 1991, 103, 56 – 70; Angew. Chem. Int. Ed. Engl. 1991, 30, 34 – 48; b) A. Muller, S. Roy in The Chemistry of Nanomaterials: Synthesis, Properties and Applications (Hrsg.: C. N. R. Rao, A. Muller, A. K. Cheetham), Wiley-VCH, Weinheim, 2004 .
- V.W.Day,W.G. Klemperer, Science 228, 4699;1985
- M.T.Pope, A.Muller, Angew. Chem. Int. Ed. Engl. 30, 34; 1991.
- A. Muller, E. Beckmann, H. Bogge, M. Schmidtmann, A. Dress, Inorganic chemistry goes protein size: a Mo368 nano-hedgehog initiating nanochemistry by symmetry breaking, Angew. Chem., Int. Ed.; 2002, 41, 1162.
- H.R.Allcock,E.C. Bissell , E.T.Shawl , Structure of a new isopolymolybdate–cyclophosphazene complex, J. Am. Chem. Soc., ;1972, 94, 8603
- A.Muller., H.Reuter, Supramolecular Inorganic Chemistry: Small Guests in Small and Large Hosts, S. Dillinger, Angew. Chem. Int. Ed. Engl. 34; 1995, 2328.
- (a)C.L. Hill , Chem. Rev;1998, 98, 1–390 (special issue onpolyoxometalates); (b) Corma A., Chem. Rev.; 1995, 95, 559; (c) A.Muller , P. Kogerler , C.Kuhmann , Chem. Commun.;1999, 1347; (d) M.T.Pope , A.Muller , Angew. Chem., Int. Ed. Engl.; 1991, 30, 34
- Nohra B., Moll H., Albelo L., Mialane P., Marrot J., Mellot-Draznieks C., O‘Keeffe M., Biboum R., Lemaire J., Keita B., Nadjo L., Dolbecq A., J. Am. Chem. Soc. ;2011,133, 13363–13374.
- D. Du ,J. Qin,D. Li , Z.Su , Y.Lan ; Chem. Soc. Rev.;2014
- J.J De Luyart Lubice, De Luyar Lubice,F.C.Etractos de las Juntas Generales Celebradas porla Real Sociedad Bascongada; 1783, 46
- (a) Berzelius, J. J. Poggend. Ann. Phys. Chem.; 1826, 6, 369. (b)M.T. Pope, A. Müller, Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines, Angew. Chem. Int. Ed. Engl. 30; 1991, 34.
- L.J. Pauling., Am. Chem. Soc.; 1929, 51, 1010–1026.
- P. Gouzerh, Che, M. Actual. Chim. ; 2006, 298, 9–22.
- Werner, A. Ber. Deutschen Chem. Ges. ; 1907, 40, 40.
- W.L. Bragg;Nature; 1912, 90, 410.
- J.F. Keggin, Nature; 1933, 132, 351
- J.F. Keggin, Proc. R. Soc. Lond. A Mater. ; 1934, 144, 75–100
- J.F. Keggin. Proc. Roy. Soc., A, The Structure and Formula of 12-Phosphotungstic Acid; 1934, 75, 144, 85.
- Bruedgam, J. Fuchs, H. Hartl and R. Palm, Angew. Chem., Int. Ed.; 1998, 37, 2668
- G.Rousseau, O. Oms, A.Dolbecq, et al. Inorg. Chem. 2011, 50, 7376–7378
- B. Hasenknopf, R. Delmont, P. Herson, et al. Eur. J. Inorg. Chem.; 2002, 1081–1087
- M.T. Pope, Heteropoly and Isopoly Oxometalates; Springer: New York, NY, USA; 1983.relojes rolex imitacion
- M.T. Pope, A. Muller, Polyoxometalate chemistry—An old field with new dimensions in several disciplines. Angew. Chem. Int. Ed.; 1991, 30, 34–48.
- I.V.Kozhevnikov, Catalysis by heteropoly acids and multicomponent polyoxometalates in liquid-phase reactions. Chem. Rev.; 1998, 98, 171–198.
- N.Mizuno, M. Misono, Heterogeneous catalysis. Chem. Rev.; 1998, 98, 199–217
- A.Muller, F. Peters, M.T. Pope, D. Gatteschi; Polyoxometalates: Very large clusters—Nanoscale magnets. Chem. Rev.; 1998, 98, 239–271.
- R.Neumann, Polyoxometalate complexes in organic oxidation chemistry. Prog. Inorg. Chem.; 1998, 47, 317–370.
- M.Sadakane, E. Steckhan, Electrochemical properties of polyoxometalates as electrocatalysts. Chem. Rev.; 1998, 98, 219–237
- C. D. Wu, C. Z. Lu, H. H. Zhuang and J. S. Huang, J. Am. Chem. Soc. ;2002, 124, 3836
- X. M. Zhang, H. S. Wu, F. Q. Zhang, A. Prikhod‘ko, S. Kuwata and P. Comba, Chem. Commun.,2004, 2046
- P. Gouzerh and M. Che, Actual Chim; 2006, 298, 9–22.
- (a) L. Pauling, J. Am. Chem. Soc., 1929, 51, 1010–1026; (b) A. Werner, Z. Anorg. Chem.;1893, 267; (c) C. W. Scheele, in Niederwalluf/Wiesbaden (reprint: original ;1793, ed. M. Sandig, ;1971(d) L. Svanberg and H. Struve, Justus Liebigs Ann. Chem.;1848, 68, 209–218; (e) H. Struve, J. Prakt. Chem.; 1854, 61, 449; (f) J.-C. G. d. Marignac, Ann. Chem. Phys.; 1864, 4, 1; (g) A. Miolati and R. Pizzighelli, J. Prakt. Chem.; 1908, 77, 417–456; (h) A. Rosenheim and J. Jaenicke, J. Prakt. Chem; 1917, 100, 304; (i) I. Lindqvist, Arkiv Kemi; 1950, 2, 349–355.
- (a) W. Friedrich, P. Knipping and M. Laue, Sitzungsber. K. Bayer. Akad. Wiss. Math. Phys. Kl, 1912, 303–322; (b) M. Laue, Phys. Z., (1913), 14, 1075–1079
- W. H. Bragg, Nature; 1912, 90, 219.
- W. L. Bragg, Nature; 1912, 90, 410.
- J. S. Anderson, Nature; 1937, 140, 850
- (a) H. T. Evans, J. Am. Chem. Soc.; 1948, 70, 1291–1292
- M. T. Pope, Heteropoly and Isopoly Oxometalates, Springer-Verlag; 1983.
- P. Gouzerh and A. Proust, Chem. Rev.; 1998, 98, 77–111.
- B. Hasenknopf, R. Delmont, P. Herson and P. Gouzerh, Eur. J. Inorg.Chem.;2002, 1081–1087.
- (a) J. Zhang, Y.-F. Song, L. Cronin and T. Liu, J. Am. Chem. Soc.; 2008, 130, 14408–14409; (b) Y.-F. Song, N. McMillan, D.-L. Long, J. Thiel, Y. L. Ding, H. S. Chen, N. Gadegaard and L. Cronin, Chem.–Eur. J.;2008, 14, 2349–2354; (c) Y.-F. Song, N. McMillan, D.-L. Long, S. Kane, J. Malm, M. O. Riehle, C. P. Pradeep, N. Gadegaard and L. Cronin, J. Am. Chem. Soc. ;2009, 131, 1340–1341; (d) Y.-F. Song, D.-L. Long, S. E. Kelly and L. Cronin, Inorg. Chem.; 2008, 47, 9137–9139; (e) Y.-F. Song, D.-L. Long and L. Cronin, Cryst Eng Comm; 2010, 12, 109–115; (f) Y.-F. Song, D.-L. Long and L. Cronin, Angew. Chem., Int. Ed.; 2007, 46, 3900–3904; (g) M. H. Rosnes, C. Musumeci, C. P. Pradeep, J. S. Mathieson, D.-L. Long, Y.-F. Song, B. Pignataro, R. Cogdell and L. Cronin, J. Am. Chem. Soc.; 2010, 132, 15490–15492
- J. Fuchs and H. Hartl, Angew. Chem., Int. Ed. Engl.; 1976, 15, 375–376.
- (a) J. Fuchs and I. Knopnadel, Z. Kristallogr. Kristallgeom. Kristallphys. Kristallchem.; 1982, 158, 165; (b) T. Duraisamy, A. Ramanan and J. Vittal, J. Mater. Chem.; 1999, 9, 763–767; (c) W. Harrison, G. Stucky and T. Gier, Acta Crystallography, Sect. C: Cryst. Struct. Commun; 1993, 49, 1900–1902. (d) L.F.Chen, K.Zhu, L.H.Bi, A.Suchopar, M.Reicke, G.Mathys, H. Jaensch, U.Kortz, R.M. Richards ; Inorg. Chem.; 2007, 46, 8457.
- J.M Clemente-Juan, E. Coronado, A. Gaita-Arino; Magnetic polyoxometalates: From molecular magnetism to molecular spintronics and quantum computing. Chem. Soc. Rev.; 2012, 41, 7464–7478
- O.Oms, A. Dolbecq, P. Mialane; Diversity in structures and properties of 3D-incorporating polyoxotungstates. Chem. Soc. Rev.; 2012, 41, 7497–7536
- H. Wang, S.Hamanaka, Y.Nishimoto, S.Irle, T.Yokoyama, H.Yoshikawa, K. Awaga ; In operand X-ray absorption fine structure studies of polyoxometalate molecular cluster batteries: Polyoxometalates as electron sponges. J. Am. Chem. Soc.; 2012, 134, 4918–4924
- M.Ammam, J. Fransaer; Ionic liquid–heteropolyacid: Synthesis, characterization, and supercapacitor study of films deposited by electrophoresis. J. Electrochem. Soc.; 2011, 158, A14–A21.
- M.Kourasi, R.G.A. Wills, A.A. Shah, F.C. Walsh, Heteropolyacids for fuel cell applications. Electrochim. Acta; 2014, 127, 454–466.
- Y.Ren, B.Yue, M.Gu, H. He; Progress of the application of mesoporous silica-supported heteropolyacids in heterogeneous catalysis and preparation of nanostructured metal oxides.
- A.Dolbecq, E. Dumas, C.R. Mayer, P. Mialane; Hybrid organic–inorganic polyoxometalate compounds: From structural diversity to applications. Chem. Rev.;2010, 110, 6009–6048.
- H. Lv, Y.V. Geletii, C. Zhao, J.W. Vickers, G. Zhu, Z.Luo, J. Song, T. Lian, D.G. Musaev, C.L. Hill;. Polyoxometalate water oxidation catalysts and the production of green fuel. Chem. Soc. Rev.; 2012, 41, 7572–7589
- R.Sivakumar, J. Thomas, M. Yoon, Polyoxometalate-based molecular/nano composites: Advances in environmental remediation by photocatalysis and biomimetic approaches to solar energy conversion. J. Photochem. Photobio. C: Photochem. Rev.; 2012, 13, 277–298
- (a) M. Misono, K. Sakata, Y. Yoneda, W. Lee, in ―Proc. 7th Int. Congr. Catal., Tokyo ;1980, 1047. Kodansha, Tokyo, Elsevier, Amsterdam; 1981 (b) M. Misono, Catal. Rev.Sci. Eng., 29, 269; 1987 (c)) M. Misono, Catal. Rev.Sci. Eng., 30, 339; 1988.
- M. T. Pope, Heteropoly and isopoly anions as oxo complexes and their reducibility to mixed-valence blues, Inorg. Chem.; 1972, 11; 1973
- I. A. Weinstock, Homogeneous-phase electron-transfer reactions of polyoxometalates, Chem. Rev.; 1998, 98, 113
- M. Sadakane and E. Steckhan, Electrochemical properties of polyoxometalates as electrocatalysts, Chem. Rev.; 1998, 98, 219
- L.C.W. Baker, L. Lebioda, J. Grochowski, H.G. Mukherjee, J. Am. Chem. Soc. 102, 3274 ;1980.
- D.E. Katsoulis, M.Τ. Pope, J. Am. Chem. Soc. 106, 2737 ;1984
- P. Gouzerh, Proust, A. Chem. ReV.; 1998, 98, 77.
- (a) K.Kamata, S. Yamaguchi, M. Kotani, K. Yamaguchi, N. Mizuno ; Angew. Chem., Int. Ed.; 2008, 47, 2407. (b) A. Sartorel, M. Carraro, G.Scorrano, R. Zorzi, S. Geremia, N.D. McDaniel, S. Bernhard, M. Bonchio ; J. Am. Chem. Soc. ;2008, 130, 5006. (c) J. Macht, M.J. Janik, M. Necurock, E. Iglesia, Angew. Chem., Int. Ed.; 2007
- (a) M. Nyman, C.R. Powers, F. Bonhomme, T.M.Alam, E.J.Maginn, D.T. Hobbs ; Chem. Mater. ; 2008, 20, 2513. (b) J.A. Ferna´ndez, X.Lo´pez, C. Bo, C. Graaf, E.J. Baerends, J.M. Poblet, J. Am. Chem. Soc. ;2007, 129, 12244. (c) A.M.Douvas, E.Makarona, N. Glezos,P. Argitis, J.A. Mielczarski, E. Mielczarski, ACS Nano;2008, 2, 733
- (a)P.P Mishra, J. Pigga, T.B.Liu, J. Am. Chem. Soc. ;2008, 130, 1548. (b) J. Schemberg, K. Schneider, U.Demmer, E. Warkentin, A.Muller, U.Ermler, Angew. Chem., Int. Ed.; 2007, 46, 2408. (c) Y.J.Zhang, Y.F. Shen, J.H. Yuan, D.X. Han, Z.J. Wang, Q.X. Zhang, L. Niu, Angew. Chem., Int. Ed.; 2006, 45, 5867.
- M.T.Pop; In Heteropoly and Isopoly Oxometalates; Springer: Berlin, 1983; Vol. 8
- M.T. Pope, A. Muller, Angew. Chem. Int. Ed. Engl. 30, 34; 1991.
- D.L. Kelpert, Inorg. Chem. 8, 1556; 1969.
- D.L. Long, P. Kgerler, L. J. Farrugia, L. Cronin, Angew. Chem. 2003, 115, 4312 – 4315; Angew. Chem. Int. Ed.; 2003, 42, 4180 – 4183.
- D.L. Long, L. Cronin, Chem. Eur. J.; 2006, 12, 3698 – 3706.
- C.Calzado, J. Clemente-Juan, E. Coronado, A. Gaita-Arino, N. Suaud; Inorg. Chem. 2008, 47, 5889-5901
- D.Long, R.Tsunashima, L. Cronin ; Angew. Chem. Int. Ed., 2010, 49, 1736 – 1758
- W.Queen; PhD Dissertation, Clemson University, Clemson, SC, 2009
- L. Pauling, The molecular structure of the tungstosilicates and related compounds, J. Am. Chem. Soc., 1929, 51, 2868
- J. F. Keggin, Structure of the molecule of 12- phosphotungstic acid, Nature ; 1933, 131, 908.
- C. L. Hill, in Polyoxometalates: Reactivity, ed. A. G. Wedd, vol. 4, pp. 679–759
- G.M. Brown; M.R. Noe-Spirlet; W.R. Bursing; H.A. Levy. Acta. Cryst. B33; 1977, 1038.
- A. Rosenheim and O. Liebknecht, Zur Kenntniss der Jodsaure und Ueberjodsaure, Justus Liebigs Ann. Chem.; 1899, 308, 40.
- M. T. Pope, Heteropoly and Isopoly oxometalates, Springer, Berlin, Heidelberg, 1983
- P. Souchay, Ions mineraux condenses, Masson et Cie, Paris, 1969.
- M. T. Pope, A. Muller, Polyoxometalate chemistry: an old field with new dimensions in several disciplines, Angew. Chem., Int. Ed., 1991, 30, 34.
- M. T. Pope and A. Muller, Polyoxometalates: From Platonic Solids to Anti-Retroviral Activity, ed., Kluwer Academic Publishers, Dordrecht, Netherlands, 1994
- J. J. Borras-Almenar, E. Coronado, A. Muller and M. T. Pope Polyoxometalate Molecular Science, ed, NATO Science Series II, vol. 98
- J. A. Mc Cleverty and T. J. Meyer, Comprehensive Coordination Chemistry. II: From Biology to Nanotechnology, ed, Elsevier, Oxford, 2004
- D.L. Long, D.-L,D. Orr, G.Seeber, J. et al.; Clust. Sci. 2003, 14, 313–324.
- C.A. Ohlin, E. M.Villa, E. J.C.Fettinger, et al. Angew. Chem. Int. Ed. 2008, 47, 5634–5636
- G.E.Sigmon, P.C. Burns ; J. Am. Chem. Soc. 2011, 133, 9137–9139.
- M.T. Pope, Heteropoly and Isopolymetalates, Springer-Verlag, New York 1983.
- D.L. Kelpert, Inorg. Chem. 8, 1556 1969
- C. Ritchie, E. Burkholder, P. Kgerler, L. Cronin, Dalton Trans. 2006, 1712 – 1714.
- C. Ritchie, C. Streb, J. Thiel, S. G. Mitchell, H. N. Miras, D.-L. Long, T. Boyd, R. D. Peacock, T. McGlone, L. Cronin, Angew.Chem. 2008, 120, 6987 – 6990; Angew. Chem. Int. Ed. 2008, 47, 6881 – 6884
- N. M. Okun, T. Anderson and C. L. Hill, J. Mol. Catal., 2003, 197, 283–290; K. Kamata, K. Yonehara, Y. Sumida, K. Yamaguchi and N. Mizuno, Science, 2003, 300, 964; A. M. Khenkin and R. Neumann, J. Am. Chem. Soc., 2002, 124, 4198; E. F. Kozhevnikova and I. V. Kozhevnikov, J. Catal., 2004, 224, 164.
- M. T. Pope, Heteropoly and Isopoly Oxometalates, Springer-Verlag, Berlin, 1983.
- D.L. Long, E. Burkholder, L. Cronin, Chem. Soc. Rev. 2007, 36,105 – 121
- C. Y. Sun, S. X. Liu, D. D. Liang, K. Z. Shao, Y. H. Ren, Z. M. Su, J. Am. Chem. Soc. 2009, 131, 1883 – 1888
- H. T. Evans, Jr and J. A. Konnert, The crystal chemistry of sherwoodite, a calcium 14-vanadoaluminate heteropolycomplex, Am. Mineral., 1978, 63, 863.
- S. A. Williams, Mendozavilite and paramendozavilite, two new minerals from Cumobabi Sonora,Bol.Mineral;1986,2,13
- N. Zou, W. L. Chen, Y. G. Li, W. L. Liu, E. B. Wang, Inorg. Chem. Commun. 2008, 11, 1367 – 1370
- D.L. Long, C. Streb, Y. F.Song, S. Mitchell, L. Cronin, J. Am. Chem. Soc. 2008, 130, 1830 – 1832.
- H. N. Miras, D.-L. Long, P. Kgerler, L. Cronin, Dalton Trans2008, 214 – 221.
- H. N. Miras, J. Yan, D.-L. Long, L. Cronin, Angew. Chem. 2008, 120, 8548 – 8551; Angew. Chem. Int. Ed. 2008, 47, 8420 – 8423
- H. N. Miras, E. F. Wilson, L. Cronin, Chem. Commun. 2009, 1297 – 1311.
- M. T. Ma, T. Waters, K. Beyer, R. Palamarczuk, P. J. S. Richardt, R. A. J. O.Hair, A. G. Wedd, Inorg. Chem. (2009), 48,598 – 606.
- Y. F. Song, D.-L. Long, S. E. Kelly, L. Cronin, Inorg. Chem. 2008, 47, 9137 – 9139.
- D.-L. Long, P. Kgerler, A. D. C. Parenty, J. Fielden, L. Cronin,Angew. Chem. 2006, 118, 4916 – 4921; Angew. Chem. Int. Ed. 2006, 45, 4798 – 4803
- D.L. Long, Y. F. Song, E. F. Wilson, P. Kgerler, S. X. Guo,A. M. Bond, J. S. J. Hargreaves, L. Cronin, Angew. Chem. 2008,120, 4456 – 4459; Angew. Chem. Int. Ed. 2008, 47, 4384 – 4387
- Miras, H. N.; Yan, J.; Long, D.L.; et al. Angew. Chem. Int. Ed. 2008, 47, 8420–8423.
- E.F. Wilson, H. Abbas, B.J. Duncombe, et al ; J. Am. Chem. Soc. 2008, 130, 13876–13884.
- E.F.Wilson, H.N. Miras, M.H.Rosnes, et al. Angew. Chem. Int. Ed. 2011, 50, 3720–3724
- C. A. Ohlin, E. M. Villa, J. C. Fettinger, W. H. Casey, Angew. Chem. 2008, 120, 8375 – 8378; Angew. Chem. Int. Ed. 2008, 47,8251 – 8254. Material
- J. Yan,D.L. Long, E. F.Wilson, L. Cronin, Angew. Chem. 2009,121, 4440 – 4444; Angew. Chem. Int. Ed. 2009, 48, 4376 – 4380
- C.P.Pradeep, D.L. Long, G.N. Newton, et al. Angew. Chem. Int. Ed. 2008, 47, 4388–4391
- N.B.Colthup,L.H.Daly,S.E Wilberley,‖Introduction to Infrared and Raman Spectroscopy‖,Academic Press,London 1975
- R.Tsunashima, C.Richmond, L.Cronin, Chem. Sci. 2012, 3, 343–348
- C.Musumeci, M.H. Rosnes, F.Giannazzo, et al. ACS Nano 2011, 5, 9992–9999.
- C. Musumeci, A. Luzio, C.P. Pradeep, et al. J. Phys. Chem. C 2011, 115, 4446–4455.
- Y.F.Song, N. McMillan, .; D.L.Long, et al. Chem. Eur. J. 2008, 14, 2349–2354
- M.S.Kaba, I.K. Song, D.C. Duncan, et al. Inorg. Chem. 1998, 37, 398–406
- W.C Roentgen,Ann. Phy.Chem; 64, 1898, 1.
- W.L. Bragg,Nature, 909, 1912, 410.
- W.L.Bragg, Proc. Cambridge Philos. Soc., 17, 1913, 43.
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