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SYNTHESIS AND CHARACTERIZATION OF POLY(ACRYLAMIDE) BY CONTROLLED RADICAL POLYMERIZATION

Rajesh Kumar

Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi-221005, UP, INDIA.

28-39

Vol: 6, Issue: 2, 2016

Receiving Date: 2016-02-20 Acceptance Date:

2016-03-14

Publication Date:

2016-04-16

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Abstract

Successful polymerization of acrylamide was carried out by controlled radical polymerization methodology. The kinetics of controlled radical polymerization was studied and it was found pseudo first order. The conversion was calculated by integration of proton of repeated units.

Keywords: POLYMERIZATION ;METHODOLOGY.

References

  1. Kato, M; Kamigaito, M; Sawamoto, M; Higashimura, T (1995). 'Polymerization of Methyl Methacrylate with the Carbon Tetrachloride/Dichlorotris-(triphenylphosphine) ruthenium (II)/Methylaluminum Bis(2,6-di-tert-butylphenoxide) Initiating System: Possibility of Living Radical Polymerization'. Macromolecules 28: 1721–1723. doi:10.1021/ma00109a056.
  2. Wang, J; Matyjaszewski, K (1995). 'Controlled/'living' radical polymerization. Atom transfer radical polymerization in the presence of transition-metal complexes'. J. Am. Chem. Soc. 117: 5614–5615.doi:10.1021/ja00125a035.
  3. Cowie, J. M. G.; Arrighi, V. In Polymers: Chemistry and Physics of Modern Materials; CRC Press Taylor and Francis Group: Boca Raton, Fl, 2008; 3rd Ed., pp 82-84.
  4. Patten, T. E; Matyjaszewski, K (1998). 'Atom Transfer Radical Polymerization and the Synthesis of Polymeric Materials'. Adv. Mater. 10: 901. doi:10.1002/(SICI)1521- 4095(199808)10:12<901::AID-ADMA901>3.0.CO;2-B.
  5. Odian, G. In Radical Chain Polymerization; Principles of Polymerization; Wiley-Interscience: Staten Island, New York, 2004; Vol. , pp 316-321.
  6. Matyjaszewski, K; Xia, J (Sep 2001). 'Atom Transfer Radical Polymerization'. Chem. Rev. 101 (9): 2921–2990. doi:10.1021/cr940534g. ISSN 0009-2665. PMID 11749397.
  7. Reynolds, W. J.; Wasser, R. B. In Pulp and Paper Chemistry and Chemical Technology. 1981 Vol. 3, Casey, J. P. Ed., Wiley-Intersciences, New York.
  8. Flock, H. G.; Rausch, E. G. In Water soluble polymers, Bikales, N. M. Ed., Plenum Press, New York 1973.
  9. Chang, H. L. J. Pet .Technology 1978, 30, 1113.
  10. Roth, R. W. U.S. Patent 1957, 2801985.
  11. Hoffman, A. S. J. Controlled Release 1987, 4, 213.
  12. Raney, B.; Zuchowska, D. Polymer J. 1987, 9(5), 623.
  13. Fuxman, A. M.; McAuley, K. B.; Schreiner, L. J. Chem Eng Sci 2005, 60, 12.
  14. Cohen, Y.; Ramon, O.; Kopelman, I. J.; Mizrahi, S. J. Polym. Sci. Part B Polym. Phys. 1992, 30, 1055.
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