This article presents a review summary of the materials commonly used in polymer -supported chemistry and their evolution. It begins Based on the extensive utility of these hypervalent iodine compounds in organic synthesis, polymer-supported reagents having (diacetoxy)iodo group (PSIBD), bis(trifluoroacetoxy)iodo groups (PS-BTI), [hydroxy(tosyloxy)iodo]group (PS-HTIB), (dichloro)iodo group (PS-DCIB) have recently been developed. Applications of polymer-supported hypervalent iodine reagents in organic synthesis have been widely studied and some of the key reactions of these are described herein.

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