SYNTHESIS OF POLYMER-SUPPORTED REAGENTS AND THEIR CATALYTIC PROPERTIES AND APPLICATIONS
Rajeev Kumar Sharma, Piyus Kumar Pathak, Sujit Chaudhari
This paper presents a review summary of hypervalent Iodine compounds reflects a wide variety
beneficial in chemical transformation. The use of hypervalent iodine reagents as catalysts in
synthetic transformations. It was planned to use polymer-supported hypervalent iodine reagents as
catalysts. These reagents are prepared by per acid oxidation of iodopolystyrene. During reaction,
stoichiometric amount of polymeric iodine (III) reagent is required and after completion of
reaction, polymeric iodine (III) reagent is reduced to monovalent iodine (I) as side product, which
was initially employed for the production of iodine (III) species as outlined.
Download PDF
References
- Anisimova, V. A.; Spasov, A. A.; Kucheryavenko, A. F.; Panchenko, T. I.; Ostrovskii, O. V.; Kosolapov, V. A.; Larionov, N. P. Pharma. Chem. J. 2002,36, 528.
- Blossey, E. C.; Turner, L. M.; Neckers, D. C. Tetrahedron Lett. 1973, 1823; J.Org. Chem. 1975, 40, 959.
- (a) Chalk, A. J. J. Polym. Sci. 1968, B6, 649. (b) Evans, D. C.; Phillips, L.; Barrie, J. A.; George, M. H. J. Polym. Sci. Polym. Chem. Ed. 1974, 12, 199. (c) Camps, F.; Castells, J.; Ferrando, M. J.; Font, J. Tetrahedron Lett. 1971,1713. (d) Weinshenker, N. M.; Crosby, G. A.; Wong, J. Y. J. Org. Chem.1975, 40, 1966.
- Cheng, D. P.; Chen, Z. C. Synth. Commun. 2002, 32, 2155.
- (a) Dalko, P. I.; Moisan, L. Angew. Chem. Int. Ed. 2004, 43, 5138. (b) Dalko, P. I.; Moisan, L. Angew. Chem. Int. Ed. 2001, 40, 3726. (c) Groger, H.; Wilken, J. Angew. Chem. Int. Ed. 2001, 40, 529.
- (a) Furka, A.; Sebestyen, F.; Asgedom, M.; Dibo, G.; Int. J. Peptide Protein Res. 1991, 37, 487. (b) Houghten, R. A. Proc. Natl. Acad. Sci. U. S. A. 1985, 82, 5131. (c) Lam, K. S.; Salmon, S. E.; Hersh, E. M.; Hruby, V. J.; Kazmierski, W. M.; napp, R. J. Nature (London) 1991, 354, 82.
- Frechet, J. M. J.; Farral, M. J.; Nuyens, L. G. J. Macromol. Sci. Chem. 1977, 507,A11.
- Frechet, J. M. J.; Darling, P.; Farral, M. J. J. Org. Chem. 1981, 46, 1728.
- (a) Frechet, J. M. J.; Farral, M. J. Chemistry and Properties of Crosslinked Resins; ed. Labna, S. S. Academic Press: New York, 1977, 59. (b) Farral, M. J.; Frechet, J. M. J. J. Org. Chem. 1976, 41, 3877. (c) Heitz, W.; Michels, R. Macromol. Chem. 1971, 148, 9.
- Frechet, J. M. J.; Smet, M. D.; Farral, M. J. Polymer 1979, 20, 675.
- (a) Frechet, J. M. J.; Warnock, J.; Farral, M. J. J. Org. Chem. 1978, 43, 2618. (b) Greig, J. A.; Sherrington, D. C. Polymer, 1978, 19, 163.
- (a) Gladysz, J. A. Chem. Rev. 2002, 102, 3215. (b) Hodge, P. Ind. Eng.Chem.Res. 2005, 44, 8542.
- Gabrielson, G.; Samuelson, O. Acta. Chem. Scand. 1952, 6, 729. Hodge, P.; Khoshdel, E. React. Polym. 1985, 3, 143.
- Helfferich, F. G. Ion Exchange; McGraw-Hill: New York, 1962, 11. (b) Hodge, P.; Sherrington , D . C. Polymer-Supported Reactions in Organic Synthesis; Eds.; John Wiley: Chichester, 1980. (c) Hodge, P.; Sherrington, D. C. Synthesis and Separations Using Functional Polymers; Eds: Chichester, 1988. (d) Hodge, P.; Sherrington, D. C. Polymer 1983, 24, 1369.
- Kamogava, H.; Odabe, S.; Nananawa, M. Bull. Chem. Soc. Jpn. 1976, 49, 1917.
- (a) Merrifield, R. B.; J. Am. Chem. Soc. 1963, 85, 2149. (b) Merrifield, R.; Stewart, J. M.; Jernberg, N. Anal. Chem. 1966, 38, 1905. (c) Gutte, B.; Merrifield, R. B. J. Biol. Chem. 1971, 246, 1922.
- (a) Neckers, D. C.; Kooistra, D. A.; Green, G. W. J. Am. Chem. Soc. 1972, 94, 9284. (b) Hirai, H.; Wakabayashi, H.; Komiyama, M. Chem. Lett. 1983, 1047.
- (a) Umemoto, T. Yuki Gosei Kagaku Kyokaishi 1983, 41, 251
Back
